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Beilstein J. Org. Chem. 2013, 9, 2182–2188, doi:10.3762/bjoc.9.256
Graphical Abstract
Scheme 1: Proposed reaction mechanism between 1 and MeLi.
Scheme 2: Furan synthesis from a mixture of 5a and 6a.
Scheme 3: Deuteration of anionic species from 4.
Figure 1: A part of 1H NMR chart of 4 and its deuterated mixture.
Scheme 4: Lithiation of 4 and the following electrophilic reactions.
Scheme 5: Alternative reaction mechanism between 1 and MeLi.